3. Blake Lively and Ryan Reynolds. As much as I loved Scarlett Johansson and Ryan Reynolds together, there is no denying he and Blake Lively make an adorable couple. The two were married September 9, 2012. Their wedding took place at Boone Hall Plantation in Mount Pleasant, North Carolina. Lively was one of the luckiest brides, being serenaded by Florence Welch at her reception. Out of all the details, what was most interesting was the arrival of their cake. It was driven all the way from Virginia to the site of their wedding.